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This review can provide new guidance for the future design and practical applications of phosphorus‐ and phosphide‐based materials used in AIBs. Finally, the existing challenges and issues are concluded and analyzed, and future perspectives and research directions are given. Representative works with design concepts, construction approaches, engineering strategies, special functions, and electrochemical results are listed and discussed in detail. Thereafter, the in‐depth working principles of diverse AIBs are discussed and predicted. In this review, the recent progress in AIBs using phosphorus‐ and phosphide‐based materials is summarized. To solve these problems, various promising solutions have been explored and utilized. However, the low electrical conductivity and large volume expansion of these materials during electrochemical reactions inhibit their practical applications. Phosphorus‐ and phosphide‐based materials with remarkable physicochemical properties and low costs have attracted significant attention as the anodes of alkali metal (e.g., Li, Na, K, Mg, Ca)‐ion batteries (AIBs). This study could provide a new avenue to synthesize the coating-containing nanocomposite additive to promote the lubrication properties of nanoparticles in oil. The interlayer sliding occurred to improve the anti-wear and anti-friction properties. More impressively, could enter the interface of friction pairs. Benefitting from the stable dispersity, ultrasmall particle size and the surface carbon layer of, the lubrication performance was significantly improved. In order to investigate the tribological properties, was modified with oleic acid as a surfactant, and the friction tests were carried out on an MRS-10A four-ball friction and wear tester.
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And the exhibited excellent lubrication performance as a lubricant additive. Here, we prepared the BN coated with carbon layer () by a novel hydrothermal coating method with pristine BN nanosheets as matrix material and glucose as carbon source. The advanced nano-additives can improve the lubrication performance of nanolubricants efficiently, which could greatly reduce energy consumption. This work may provide some new insights into alloy reaction of crystalline phosphorus and demonstrate a promising new anode design strategy for next-generation batteries. It is believed that the good electrochemical Na-ion storage performance of the CRP-rGA composite can be attributed to high dispersion of CRP in rGA, strong interaction between CRP and rGA together with unique porous structure of the electrode. The evolutions of CRP-rGA during charging and discharging have also been investigated systematically through ex-situ characterizations such as XPS, TEM, Raman and SEM. For instance, with an ultra-high P loading (75.9%) in the electrode, it delivers an initial specific capacity of 2427 mA h g⁻¹ (93.5% of the theoretical capacity) with Columbic efficiency of ∼82% at 0.1 A g⁻¹, and the relatively higher capacity can be retained at 1 and 2 A g⁻¹ with progressive cycling.
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The unique composite was investigated as anode for sodium-ion batteries (SIBs) for the first time and presents competitive sodium storage performance. Herein, we successfully construct crystalline red P (CRP) nanorods confined within 3D rGA (CRP-rGA) architecture composite via prepositioned nanoseeds following with secondary growth method. To be noted that, amorphous red P (RP) is universally used as the SIB anodic material in most of the reported works. Nevertheless, its practical applications suffer from huge volumetric change during cycling and low electronic conductivity with the result of fast capacity decay and low Coulombic efficiency (CE). Phosphorus (P) has been regarded as one of promising anodic materials for Li- and Na-ion batteries owing to the merits of high theoretical specific capacity and natural abundance.